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LBO

 

Description:

   Lithium Triborate (LiB3O5 or LBO) is an attractive nonlinear optical crystal.

 

Features:

  • Broad transparency range from 160nm in UV to 2600nm in IR; 

  • High optical homogeneity (dn~10-6/cm) and being free of inclusion; 

  • Relatively large effective SHG coefficient (about three times that of KDP); 

  • High damage threshold (>10GW/cm2 for 1064nm, 20ns, 50Hz); 

  • High effective non-linear coefficient ,wide acceptance angle and small walk-off; 

  • Type I and type II non-critical phase matching (NCPM) in a wide wavelength range; 

  • Spectral NCPM near 1300nm;

  • Absorption: <30ppm/cm @1064nm <50ppm/cm for high power laser application.

 

Applications:

  • SHG and THG for middle and high power Nd: lasers at 1064nm for medical, industrial and military applications; 

  • SHG for Ti:Sapphire, Alexandrite and Cr:LiSAF lasers; 

  • SHG and THG of high power Nd: lasers at 1342nm & 1319nm for red and blue laser; 

  • SHG for the Nd: Lasers at 914nm & 946nm for blue laser; 

  • The VUV output at 187.7 nm is obtained by sum-frequency generation; 

  • NCPM SHG over a broad wavelength range from 900nm-1700nm was measured;

  • Phase matching process: SHG-554 nm fundamental, THG-794 nm, SFM-down to 160 nm; 

  • Optical Parametric Amplifiers (OPA) and Oscillators (OPO) application.

 

Physical and Chemical Properties:

Crystal Structure Orthorhombic, Space group Pna21, Point group mm2
Lattice Parameters (Å)a=8.4473, b=7.3788, c=5.1395, Z=2
Melting Point (°C)~ 834
Mohs Hardness~6
Density (gram/cm3)~ 2.47
Hygroscopic Susceptibilitylow
Thermal Conductivity (W/m/K)3.5
Thermal Expansion Coefficientαx=10.8x10-5/K, αy= -8.8x10-5/K, αz=3.4x10-5/K

 

Optical and Nonlinear Optical Properties:

Transparency Range160 - 2600 nm
Phase Matching Range551-2600nm for Type I, 790-2150nm for Type II
Thermo-Optic Coefficients (℃-1, λ in μm)dnx/dT = - 9.3 x 10-6
dny/dT = -13.6 x 10-6
dnz/dT = (-6.3+2.1λ) x 10-6
Sellmeier Equations (λ in μm)n2x= 2.4542+0.01125/(λ2-0.01135)-0.01388λ2
n2y=2.5390+0.01277/(λ2-0.01189)-0.01848λ2
n2z=2.5865+0.01310/(λ2-0.01223)-0.01861λ2
Non-Vanished Nonlinear Susceptibilitiesd31 = 1.05 ± 0.09 pm/V
d32 = -0.98 ± 0.09 pm/V
d33= 0.05 ± 0.006 pm/V

 

Specifications:

Aperturesup to 30 x 30mm2
Lengthup to 50mm
Dimension Tolerance(W ± 0.1mm) x (H ± 0.1mm) x (L + 0.2mm/-0.1mm)
Phase Matching Angle Tolerance∆θ< ± 0.25°; ∆φ< ±0.25°
Flatnessλ/10 @ 633nm
Wavefront Distortionλ/10 @ 633nm
Surface Quality10/5 Scratch/Dig
Parallelism10 arc seconds
Perpendicularity3 arc minutes
Clear Aperture≥95% central area