LBO
Description:
Lithium Triborate (LiB3O5 or LBO) is an attractive nonlinear optical crystal.
Features:
Broad transparency range from 160nm in UV to 2600nm in IR;
High optical homogeneity (dn~10-6/cm) and being free of inclusion;
Relatively large effective SHG coefficient (about three times that of KDP);
High damage threshold (>10GW/cm2 for 1064nm, 20ns, 50Hz);
High effective non-linear coefficient ,wide acceptance angle and small walk-off;
Type I and type II non-critical phase matching (NCPM) in a wide wavelength range;
Spectral NCPM near 1300nm;
Absorption: <30ppm/cm @1064nm <50ppm/cm for high power laser application.
Applications:
SHG and THG for middle and high power Nd: lasers at 1064nm for medical, industrial and military applications;
SHG for Ti:Sapphire, Alexandrite and Cr:LiSAF lasers;
SHG and THG of high power Nd: lasers at 1342nm & 1319nm for red and blue laser;
SHG for the Nd: Lasers at 914nm & 946nm for blue laser;
The VUV output at 187.7 nm is obtained by sum-frequency generation;
NCPM SHG over a broad wavelength range from 900nm-1700nm was measured;
Phase matching process: SHG-554 nm fundamental, THG-794 nm, SFM-down to 160 nm;
Optical Parametric Amplifiers (OPA) and Oscillators (OPO) application.
Physical and Chemical Properties:
Crystal Structure | Orthorhombic, Space group Pna21, Point group mm2 |
Lattice Parameters (Å) | a=8.4473, b=7.3788, c=5.1395, Z=2 |
Melting Point (°C) | ~ 834 |
Mohs Hardness | ~6 |
Density (gram/cm3) | ~ 2.47 |
Hygroscopic Susceptibility | low |
Thermal Conductivity (W/m/K) | 3.5 |
Thermal Expansion Coefficient | αx=10.8x10-5/K, αy= -8.8x10-5/K, αz=3.4x10-5/K |
Optical and Nonlinear Optical Properties:
Transparency Range | 160 - 2600 nm |
Phase Matching Range | 551-2600nm for Type I, 790-2150nm for Type II |
Thermo-Optic Coefficients (℃-1, λ in μm) | dnx/dT = - 9.3 x 10-6 |
dny/dT = -13.6 x 10-6 | |
dnz/dT = (-6.3+2.1λ) x 10-6 | |
Sellmeier Equations (λ in μm) | n2x= 2.4542+0.01125/(λ2-0.01135)-0.01388λ2 |
n2y=2.5390+0.01277/(λ2-0.01189)-0.01848λ2 | |
n2z=2.5865+0.01310/(λ2-0.01223)-0.01861λ2 | |
Non-Vanished Nonlinear Susceptibilities | d31 = 1.05 ± 0.09 pm/V |
d32 = -0.98 ± 0.09 pm/V | |
d33= 0.05 ± 0.006 pm/V |
Specifications:
Apertures | up to 30 x 30mm2 |
Length | up to 50mm |
Dimension Tolerance | (W ± 0.1mm) x (H ± 0.1mm) x (L + 0.2mm/-0.1mm) |
Phase Matching Angle Tolerance | ∆θ< ± 0.25°; ∆φ< ±0.25° |
Flatness | λ/10 @ 633nm |
Wavefront Distortion | λ/10 @ 633nm |
Surface Quality | 10/5 Scratch/Dig |
Parallelism | 10 arc seconds |
Perpendicularity | 3 arc minutes |
Clear Aperture | ≥95% central area |